On the three-center orbital projection formalism within the electron density of delocalized bonds method
Sign Up to like & getrecommendations! Published in 2017 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2016.12.003
Abstract: Abstract A new development of the Electron Density of Delocalized Bonds formalism (EDDB) is proposed that provides marked improvement in the description of electron delocalization in aromatic rings. Special attention is paid to charged aromatic… read more here.
Keywords: three center; density delocalized; delocalized bonds; electron ... See more keywords
Tridentate Ligand with Three Carbanions as Donor Atoms: Formation of Dinuclear, Heptacyclic Complexes of Boron, Aluminum, or Gallium with B-C-B, Al-C-Al, or Ga-C-Ga Three-Center-Two-Electron Bonds.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00254
Abstract: The trilithium compound 1,3-[PhMe2Si-C(Li)═C(H)]2C6H3Li (2b) reacted with BCl3, AlCl3, or GaCl3 by salt elimination to yield dinuclear heptacyclic compounds (4). Two tridentate tricarbanionic ligands coordinate two B, Al, or Ga atoms and adopt a helical… read more here.
Keywords: three center; electron bonds; center two; chemistry ... See more keywords
Molecular and Electronic Structures of M2O7 (M = Mn, Tc, Re).
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b02503
Abstract: The molecular and electronic structures of the group 7 heptoxides were investigated by computational methods as both isolated molecules and in the solid-state. The metal-oxygen-metal bending angle of the single molecule increased with increasing atomic… read more here.
Keywords: molecular electronic; electronic structures; bond; three center ... See more keywords
Carbon's Three-Center, Four-Electron Tetrel Bond, Treated Experimentally.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b09367
Abstract: Tetrel bonding is the noncovalent interaction of group IV elements with electron donors. It is a weak, directional interaction that resembles hydrogen and halogen bonding yet remains barely explored. Herein, we present an experimental investigation… read more here.
Keywords: four electron; bond; tetrel bond; three center ... See more keywords
LMO1 Gene Polymorphisms Reduce Neuroblastoma Risk in Eastern Chinese Children: A Three-Center Case-Control Study
Sign Up to like & getrecommendations! Published in 2018 at "Frontiers in Oncology"
DOI: 10.3389/fonc.2018.00468
Abstract: Background: Neuroblastoma, a neuroendocrine tumor, stems from the developing sympathetic nervous system. Previous genome-wide association studies (GWASs) have discovered a number of neuroblastoma susceptibility genes in Caucasians including LIM domain only 1 (LMO1). Objective: We… read more here.
Keywords: risk; three center; center case; eastern chinese ... See more keywords