A new series of three-coordinate cuprous complexes formed by steric hindrance of a phosphine ligand: Synthesis, structure characterization, properties and TD-DFT calculations
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114178
Abstract: Abstract Four new three-coordinate cuprous complexes with a CuN2P core, 1-QBO, 2-Phen, 3-MePBO, 4-QBI, were designed and synthesized by utilizing a steric hindrance of phosphine ligand o-Anisyl3P [QBO = 2-(2′-quinolyl)benzoxazole, Phen = 1,10-Phenanthroline, MePBO = 5-methyl-2-(2′-pyridyl)-benzoxazole, QBI = 2-(2′-quinolyl)benzimidazole, o-Anisyl3P = tri(2-methoxyphenyl)-phosphine]. As a counterpart… read more here.
Keywords: phosphine ligand; phosphine; coordinate cuprous; three coordinate ... See more keywords
Three-Coordinate Pd(0) with Rare-Earth Metalloligands: Synergetic CO Activation and Double P-C Bond Cleavage-Formation Reactions.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00990
Abstract: Metalation of β-diketiminato rare-earth metal complexes LnacnacLn(PhNCH2PPh2)2 (Ln = Y, Yb, Lu) with (COD)Pd(CH2SiMe3)2 afforded three-coordinate Pd(0) complexes supported by two sterically less bulky phosphines and a Pd → Ln dative interaction. The Pd(0) center… read more here.
Keywords: bond; rare earth; bond cleavage; formation ... See more keywords
Deciphering the Role of Symmetry and Ligand Field in Designing Three-Coordinate Uranium and Plutonium Single-Molecule Magnets.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02646
Abstract: Actinide single-molecule magnets (SMMs) have gained paramount interest in molecular magnetism as they offer a larger barrier height of magnetization (Ueff) reversal compared to the lanthanide analogue, thanks to their greater metal-ligand covalency. However, the… read more here.
Keywords: single molecule; three coordinate; molecule magnets; geometry ... See more keywords
A new strategy to synthesize three-coordinate mononuclear copper(i) halide complexes containing a bulky terphenyl bidentate phosphine ligand and their luminescent properties
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c8nj05605f
Abstract: Three mononuclear three-coordinate Cu(i) halide complexes were synthesized by a new strategy and they exhibit green to yellow green emission in the solid state at room temperature. read more here.
Keywords: new strategy; halide complexes; three coordinate;
Isolation and characterization of a blue coloured three coordinate Cu(I)-radical complex with an S3 donor set.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc03777d
Abstract: A stable three coordinate Cu(I)-radical complex with an S3 donor set having the general formula of [CuI(S-NHCH)(SS-NHCS)] (1) was isolated as dark blue needles. Interestingly, this complex possesses a zwitterionic ligand, -S-NHCH+, which is coordinated… read more here.
Keywords: coordinate radical; three coordinate; donor set; complex donor ... See more keywords
Crystal structure of a three-coordinate lithium complex with monodentate phenyloxazoline and hexamethyldisilylamide ligands
Sign Up to like & getrecommendations! Published in 2024 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989024004237
Abstract: The reaction between lithium hexamethyldisilazane, [Li{N(Si(CH3)3)2}] (LiHMDS), with 4,4-dimethyl-2-phenyl-2-oxazoline (Phox) in hexane produced the title complex [Li{N(Si(CH3)3)2}(Phox)2]. The molecule, which crystallizes in the C2/c space group, lies on a twofold rotation axis and the lithium… read more here.
Keywords: lithium; three coordinate; crystal structure; coordinate lithium ... See more keywords