Three polyoxometalate-tuned copper complexes based on in situ ligand transformation: syntheses, structures, and properties
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DOI: 10.1080/00958972.2020.1825698
Abstract: Abstract Depending on the in situ ligand transformation of 3,5-di(1,2,4-triazol-1-yl)benzonitrile (DTCN) to 3,5-di(1,2,4-triazol-1-yl)benzoic acid (DTCA) under hydrothermal condition, three polyoxometalate-based copper complexes, [CuI 4CuII 2(OH)2(H2O)4(DTCA)4(HPMoVI 10MoV 2O39)] (1), [Cu4(OH)2(H2O)4(DTCA)2(SiW12O40)]·11H2O (2), and {Cu2Cl(H2O)(HDTCA)2[CrMo6(OH)6O18)]}·4H2O (3), have been… read more here.
Keywords: situ ligand; three polyoxometalate; copper complexes; ligand transformation ... See more keywords