Sequence-Controlled Synthesis of Advanced Clickable Synthetic Oligonucleotides.
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202000327
Abstract: Through thiol-ene photopolymerization of presynthesized oligomers, advanced clickable nucleic acids (CNA-2G) are synthesized with sequence-controlled repeating units. As examples, poly(thymine-adenine) (polyTA) CNA-2G and poly(thymine-thymine-cytosine) CNA-2G are synthesized by polymerizing thiol-ene heterofunctional dimers with pendant thymine-adenine… read more here.
Keywords: growth propagation; thiol ene; sequence controlled; advanced clickable ... See more keywords
Experimental and Theoretical Study of Strong Low-Terahertz Absorption of Thymine
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Infrared, Millimeter, and Terahertz Waves"
DOI: 10.1007/s10762-017-0420-z
Abstract: The absorption coefficient of a nucleobase-thymine-in powder form was measured with terahertz spectroscopy in both frequency- and time-domain experiments. For frequencies below 3 THz, a strong signature was observed at 1.27 THz. Furthermore, molecular-dynamic simulations… read more here.
Keywords: absorption; theoretical study; experimental theoretical; study strong ... See more keywords
Au NP-Decorated g-C3N4-Based Photoelectochemical Biosensor for Sensitive Mercury Ions Analysis
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c01335
Abstract: Herein, an efficient and feasible photoelectrochemical (PEC) biosensor based on gold nanoparticle-decorated graphitic-like carbon nitride (Au NPs@g-C3N4) with excellent photoelectric performance was designed for the highly sensitive detection of mercury ions (Hg2+) . The proposed… read more here.
Keywords: thymine; mercury ions; detection; biosensor ... See more keywords
Denaturation of dsDNA Induced by Specific Major Groove Binding of Cadmium Ion to Thymine
Sign Up to like & getrecommendations! Published in 2017 at "ACS Omega"
DOI: 10.1021/acsomega.7b01377
Abstract: The toxicity of cadmium causes varying degrees of risk to organisms. The underlying mechanism has been conventionally attributed to Cd2+-ion-induced oxidative stress. Here, we propose that the Cd2+ ion directly and stably binds with the… read more here.
Keywords: major groove; ion; cadmium; thymine ... See more keywords
Sequence-dependent thymine dimerization and lifetimes of the photoexcited state of oligonucleotides.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03902h
Abstract: DNA-sequence-dependent thymine-thymine (TT) dimerization was investigated from the perspective of the UV-induced charge transfer state. Steady-state and transient absorption measurements suggest that the relatively small oxidation potential and long-lived charge transfer state at the neighboring… read more here.
Keywords: thymine; state; sequence dependent; dependent thymine ... See more keywords
Photochemistry of Thymine in Protic Polar Nanomeric Droplets Using Electrostatic Embeding TD-DFT/MM
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26196021
Abstract: Thymine photochemistry is important for understanding DNA photodamage. In the gas phase, thymine undergoes a fast non-radiative decay from S 2 to S 1 . In the S 1 state, it gets trapped for several… read more here.
Keywords: nanomeric droplets; protic polar; polar nanomeric; thymine protic ... See more keywords