Tin(II) 2-ethylhexanoate and ascorbic acid as reducing agents in solution ARGET ATRP: A kinetic study approach by mathematical modeling and simulation
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2019.01.123
Abstract: Abstract The mechanism of activators regenerated by electron transfer (ARGET) associated with atom transfer radical polymerization (ATRP) has attracted attention because of the transition metal catalyst reduction in the conventional ATRP process. In this paper,… read more here.
Keywords: reducing agents; solution arget; tin ethylhexanoate; ethylhexanoate ascorbic ... See more keywords
ROPs of l-lactide catalyzed by neat Tin(II)2-ethylhexanoate - Influence of the reaction conditions on Tm and ΔHm
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DOI: 10.1016/j.polymer.2021.124122
Abstract: Abstract l -Lactide was polymerized by means of neat SnOct2 with variation of LA/Cat ratio, temperature and time. The resulting cyclic polylactides crystallized spontaneously at 160 °C or below, but needed nucleation via mechanical stress at… read more here.
Keywords: lactide catalyzed; ethylhexanoate influence; tin ethylhexanoate; neat tin ... See more keywords
High molar mass cyclic poly(l-lactide) obtained by means of neat tin(ii) 2-ethylhexanoate
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DOI: 10.1039/d0py00811g
Abstract: L-Lactide was polymerized in bulk at 120, 140, 160 and 180 °C with neat tin(II) 2-ethylhexanoate (SnOct2) as the catalyst. At 180 °C the Lac/Cat ratio was varied from 25/1 up to 8000/1 and at… read more here.
Keywords: tin ethylhexanoate; mass; tin; lac cat ... See more keywords