Construction of Novel Cyclic Tetrads by Axial Coordination of Thiaporphyrins to Tin(IV) Porphyrin.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b01966
Abstract: We report the formation of new cyclic porphyrin tetrads 1 and 2, which were obtained from the reaction between dihydroxytin(IV) porphyrin and cis-dihydroxy-21-thiaporphyrin/21,23-dithiaporphyrin. The unique oxophilicity of tin(IV) porphyrin was the driving force for the… read more here.
Keywords: novel cyclic; cyclic tetrads; construction novel; tin porphyrin ... See more keywords
A tin porphyrin axially-coordinated two-dimensional covalent organic polymer for efficient hydrogen evolution.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02775e
Abstract: Herein, we demonstrate a facile strategy for constructing an efficient and stable hydrogen evolution reaction (HER) catalyst, i.e. a tin porphyrin axially-coordinated 2D covalent organic polymer (SnTPPCOP). SnTPPCOP exhibits promising HER activity with a low… read more here.
Keywords: organic polymer; covalent organic; tin porphyrin; axially coordinated ... See more keywords