Understanding titanium-catalysed radical-radical reactions: a DFT study unravels the complex kinetics of ketone-nitrile couplings.
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DOI: 10.1039/c8dt00643a
Abstract: The computational investigation of a titanium-catalysed reductive radical-radical coupling is reported. The results match the conclusions from an earlier experimental study and enable a further interpretation of the previously observed complex reaction kinetics. Furthermore, the… read more here.
Keywords: radical radical; understanding titanium; study; titanium ... See more keywords
Titanium-catalysed deoxygenation of benzylic alcohols and lignin model compounds
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DOI: 10.1039/d3qo00623a
Abstract: We report a catalytic system for direct deoxygenation of benzylic alcohols by using non-precious precatalyst Cp2TiCl2 and 2 MeTHF as solvent. Mechanistic studies showed that the used silane Me(EtO)2SiH acts... read more here.
Keywords: catalysed deoxygenation; benzylic alcohols; titanium catalysed; deoxygenation benzylic ... See more keywords