Antidiabetic and antioxidant studies of novel synthesized titanium (IV) complex: Design, synthesis, in‐silico docking and in‐vitro studies
Sign Up to like & getrecommendations! Published in 2024 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.7443
Abstract: [{TiCl3}2(C3N3S3H)] (where C3N3S3H is Trithiocyanuric acid) was designed and synthesized by the reaction of TiCl4 and trithiocyanuric acid in 2:1 M ratio under stirring and refluxing condition using THF solvent. The synthesized Titanium (IV) complex was… read more here.
Keywords: antioxidant studies; synthesized titanium; titanium complex; silico docking ... See more keywords
Impact of polydimethylsiloxanes on physicochemical and tribological properties of naphthenic mineral oil (KN 4010)-based titanium complex grease
Sign Up to like & getrecommendations! Published in 2019 at "Chinese Journal of Chemical Engineering"
DOI: 10.1016/j.cjche.2018.09.002
Abstract: Abstract Titanium complex greases were prepared by using naphthenic mineral oil and polydimethylsiloxane as the mixed base oil. The effect of polydimethylsiloxane molecular weight and polydimethylsiloxane content in mixed base oil on the physicochemical and… read more here.
Keywords: mineral oil; tribological properties; oil; titanium complex ... See more keywords
Efficient and chemoselective hydroboration of organic nitriles promoted by TiIV catalyst supported by unsymmetrical acenaphthenequinonediimine ligand
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.120958
Abstract: Abstract We report the synthesis, characterization, and utilization of a titanium (IV) complex [(η5-C5H5){L}TiCl2] (1) supported by a monoanionic ligand (L), N-(2, 6-diisopropyl)acenaphthenequinonediimido, as a molecular pre-catalyst for the hydroboration of nitriles. The unsymmetrical N-silylated… read more here.
Keywords: catalyst; titanium complex; acenaphthenequinonediimine ligand; ligand ... See more keywords
Microstructure of titanium on complex deformation paths: Comparison of ECAP, KOBO and HE techniques
Sign Up to like & getrecommendations! Published in 2018 at "Materials Characterization"
DOI: 10.1016/j.matchar.2018.04.037
Abstract: Abstract In this work samples of commercial purity grade 2 titanium were severely deformed by three different extrusion techniques: equal-channel angular pressing (ECAP), extrusion through oscillating die (KOBO), and hydrostatic extrusion (HE). Resulting microstructures and… read more here.
Keywords: complex deformation; kobo; titanium complex; deformation ... See more keywords
Well-Defined Titanium Complex for Free-Radical and Cationic Photopolymerizations under Visible Light and Photoinduction of Ti-Based Nanoparticles
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.8b02719
Abstract: A quinoline-derived titanium complex (TiQ) is shown here to possess remarkable photosensitizing properties when treated with an iodonium salt (Iod) to initiate, under visible light irradiation, (i) the free-radical photopolymerization of acrylate monomer in aerated/laminate… read more here.
Keywords: free radical; microscopy; radical cationic; based nanoparticles ... See more keywords
Reaction of a bis(pentafulvene)titanium complex with an N-heterocyclic olefin: C-H-activation leads to resonance between a titanium vinyl and titanium alkylidene complex.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00014h
Abstract: The N-heterocyclic olefin (NHO) ImMe4CH2 (2) (ImMe4CH2 = (MeCNMe)2CCH2) was employed for the synthesis of the titanium complex 3 derived from an NHO ligand precursor. By reacting 2 with the bis(π-η5:σ-η1-pentafulvene)titanium complex 1a, the terminal… read more here.
Keywords: pentafulvene titanium; bis pentafulvene; titanium vinyl; heterocyclic olefin ... See more keywords
Tribo-synergism in titanium complex grease using micro and nano particles
Sign Up to like & getrecommendations! Published in 2025 at "PLOS One"
DOI: 10.1371/journal.pone.0323444
Abstract: Micro-nano additive-enhanced lubricating greases are pivotal for extreme-condition tribology, yet optimizing synergistic additive concentrations remains constrained by conventional experimental designs. This study employs a central composite design (CCD) coupled with MATLAB response surface methodology to… read more here.
Keywords: complex grease; titanium complex; grease; tribo synergism ... See more keywords