Titanium(III) Sulfide Nanoparticles Coated with Multicomponent Oxide (Ti–S–O) as a Conductive Polysulfide Scavenger for Lithium–Sulfur Batteries
Sign Up to like & getrecommendations! Published in 2019 at "Electronic Materials Letters"
DOI: 10.1007/s13391-019-00153-8
Abstract: In spite of the high specific capacity and energy density of Li–S batteries based on low-cost sulfur as the active material, their practical use has not yet been realized due to the undesirable formation of… read more here.
Keywords: multicomponent oxide; ti2s3; titanium iii; iii sulfide ... See more keywords
Reactivity study of a β-diketiminate titanium(III) complex with a phosphanylphosphido ligand towards chlorophosphanes. A new method of synthesis of β-diketiminate titanium(IV) complexes with versatile phosphanylphosphinidenes
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.04.051
Abstract: Abstract The reactivity of a β-diketiminate titanium(III) complex with a phosphanylphosphido ligand, [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}] (1) (MeNacNac− = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2Ph), was investigated towards selected chlorophosphanes, such as tBu2PCl, iPr2PCl, Cy2PCl, (Cy)tBuPCl, (Me)tBuPCl, (Ph)tBuPCl, Ph2PCl, (iPr2N)tBuPCl and (Et2N)2PCl. The reactions… read more here.
Keywords: diketiminate titanium; menacnacti; tbupcl; titanium ... See more keywords
Reliability in Standardization of Iron(III) and Titanium(III) Solutions in Volumetric Analysis
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DOI: 10.1021/acsomega.1c03074
Abstract: Titanium(III) is a useful strong reductant and is usually standardized with iron(III) in volumetric analysis. Iron(III) is widely used as an oxidant and is usually standardized with thiosulfate ions through an iodine liberation reaction. The… read more here.
Keywords: titanium iii; iii; iron iii; titration ... See more keywords
A titanium(III) phosphite exhibits polymorph-distinct redox activity involving proton-coupled electron transfer.
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DOI: 10.1039/d1cc01190a
Abstract: A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with subsequent photoreduction, the redox cycle… read more here.
Keywords: iii phosphite; electron transfer; proton; titanium iii ... See more keywords