Synthesis and Complexation of a Free Germanide Bearing a Tridentate N-Heterocyclic Substituent
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DOI: 10.1021/acs.organomet.8b00630
Abstract: The tris-N-heterocycle germanide (tmim)Ge– (1) (tmimH3 = tris(3-methylindol-2-yl)methane) was synthesized by nucleophilic substitution for the tmim3– trianion on GeCl2·dioxane. In combination with the previously reported (tmim)Si– and (tmim)P analogues, it provides a convenient model for… read more here.
Keywords: synthesis complexation; complexation free; germanide; tmim tmim ... See more keywords