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Published in 2018 at "Journal of Thermal Analysis and Calorimetry"
DOI: 10.1007/s10973-018-7228-5
Abstract: To investigate the effect of operational parameter and transport phenomena on para-xylene production from toluene methylation with methanol, a fixed bed tubular reactor packed with Al-HMS-5 mesoporous catalyst was numerically studied. A mechanistic Longmuir–Hinshelwood-type kinetic…
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Keywords:
methylation;
temperature;
reaction;
para xylene ... See more keywords
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Published in 2017 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.7b02187
Abstract: Investigating the mass transfer of toluene methylation with methanol will contribute to converting more methanol feedstock into the para-methyl group. The reaction system was considered as three competing reactions: toluene methylation and isomerization of para-xylene…
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Keywords:
methylation;
mass transfer;
toluene methylation;
methyl group ... See more keywords
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Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c05817
Abstract: Toluene methylation using methanol offers a high potential molecular engineering process to produce p-xylene (PX) based on shape-selective catalysts. To further improve the process economics, a novel short process was proposed by reducing the high-energy…
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Keywords:
selectivity;
xylene;
short process;
process ... See more keywords