An Auxiliary Approach for the Stereoselective Synthesis of Topologically Chiral Catenanes
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DOI: 10.1016/j.chempr.2019.03.008
Abstract: Summary Catenanes, molecules in which two rings are threaded through one another like links in a chain, can form as two structures related like an object and its mirror image but otherwise identical if the… read more here.
Keywords: synthesis topologically; topologically chiral; chiral catenanes; stereoselective synthesis ... See more keywords
A Co-conformationally “Topologically” Chiral Catenane
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02029
Abstract: Catenanes composed of two achiral rings that are oriented (Cnh symmetry) because of the sequence of atoms they contain are referred to as topologically chiral. Here, we present the synthesis of a highly enantioenriched catenane… read more here.
Keywords: chiral catenane; conformationally topologically; topologically chiral;