Enhanced Activity in the Tosylation of Tolanophanes via Supramolecular HgCl2 Recognition
Sign Up to like & getrecommendations! Published in 2020 at "Australian Journal of Chemistry"
DOI: 10.1071/ch18376
Abstract: The ‘self-activation’ of host molecules via the incorporation of a guest has received considerable attention in supramolecular catalysis. Here, we demonstrate how HgCl2 effects the tosylation rate of tolanophanes (1a–c: n = 2−4) with different alkyl chain… read more here.
Keywords: tosylation; tosylation tolanophanes; enhanced activity; hgcl2 ... See more keywords
Crystal structure and antidiabetic activity of 2-aminospiropyrazolinium tosylates and the product of O-tosylation of β-(benzimidazol-1-yl)propioamidoxime.
Sign Up to like & getrecommendations! Published in 2022 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229622008464
Abstract: 2-Amino-1,5-diazaspiro[4.5]dec-1-en-5-ium salts possess bioactivity tuned by the nature of the heteroatoms in the six-membered ring and the counter-ion. The molecular environment of these cations in solids provides an opportunity to establish the conformations and hydrogen-bonding… read more here.
Keywords: benzimidazol; dec ium; diazaspiro dec; tosylation ... See more keywords