Nickel-Catalyzed Multicomponent Assembly of Alkynes toward α-CF3-Alkenes.
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DOI: 10.1021/acs.orglett.4c01975
Abstract: We disclose an efficient nickel catalytic system for expediting the coupling of alkynes with fluoroalkyl hydrazones and boronic acids, thus facilitating the synthesis of stereospecific α-fluoroalkyl-alkene derivatives. 3H-Pyrazoles might be involved as key intermediates through… read more here.
Keywords: assembly alkynes; toward cf3; alkynes toward; catalyzed multicomponent ... See more keywords