Towards enantiopure macrocyclic trans-dinucleating hemilabile P-Alkene ligands: Syntheses, structures, and Chiral Pd-Complexes
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DOI: 10.1016/j.jorganchem.2019.120876
Abstract: Abstract Dibenzazepinyl dichlorophosphine 2 reacts with (R,R)-2,3-O-isopropylidene-threitol (3) in Et2O solution to afford gram-quantities of the enantiopure macrocylic phosphoramidite (all-R)-6, which may be seen as a formal dimer of classic phosphoramidite P-alkene hybrid ligands. Complexation… read more here.
Keywords: dinucleating hemilabile; towards enantiopure; trans dinucleating; macrocyclic trans ... See more keywords