An Azide Adduct of Ti(II) with a Sterically Encumbering Trityl Azide and Independent Synthesis of a Bulky Ti(IV) Imido and Its Isomer.
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DOI: 10.1021/acs.inorgchem.4c04975
Abstract: We report here the synthesis and characterization of a bulky titanium(IV) imido via the bimolecular deazotation of trityl azide by the Ti(II) precursor [(Tp3-tBu,5-Me)TiCl] (1, Tp3-tBu,5-Me = hydrido(tris(3-methyl-5-tert-butylpyrazolyl)borate)). The sterically encumbering trityl substituent on an… read more here.
Keywords: tbu; trityl azide; tp3 tbu; encumbering trityl ... See more keywords