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Published in 2021 at "ChemSusChem"
DOI: 10.1002/cssc.202101657
Abstract: Catalytic water oxidation is an important process for the development of future clean energy solutions and energy storage. Despite a significant number of reported active catalysts, systematic control of the catalytic activity remains elusive. Here,…
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Keywords:
water oxidation;
water;
tpy;
catalytic activity ... See more keywords
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Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200004
Abstract: Terpyridine (tpy)-based three-dimensional (3D) discrete metallo-supramolecular architectures, which are often inspired by the biological structures found in nature, have drawn significant attention from the community of metallo-supramolecular chemistry. Because of the linear tpy-M(II)-tpy connectivity, however,…
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Keywords:
discrete metallo;
metallo supramolecular;
metallo;
tpy ... See more keywords
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Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114677
Abstract: Abstract This paper presents the synthesis and characterization of [Co(Fc-tpy)2](PF6)2 complex which acts as an active electrocatalyst for H2 evolution in both organic and aqueous media (Fc-tpy = 4′-ferrocenyl-2,2′:6′,2″-terpyridine). It exhibits the electrocatalytic H2 evolution in the…
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Keywords:
evolution;
tpy;
mechanistic study;
kinetics mechanistic ... See more keywords
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Published in 2023 at "ACS Omega"
DOI: 10.1021/acsomega.3c01006
Abstract: The synthesis, electrochemistry, and photophysical characterization of five 2,2′:6′,2″-terpyridine ruthenium complexes (Ru-tpy complexes) is reported. The electrochemical and photophysical behavior varied depending on the ligands, i.e., amine (NH3), acetonitrile (AN), and bis(pyrazolyl)methane (bpm), for this…
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Keywords:
state;
low temperature;
terpyridine;
tpy ... See more keywords
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Published in 2018 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b01815
Abstract: A new irreversible solvatochromic Zn-nanopaper has been produced through the coordination-driven assembly of Zn(II)-terpyridine complex (Zn-tpy) on the surface of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-oxidized cellulose nanofibril (tCNF). The Zn-tpy as a photoactive center exhibits a changed emission…
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Keywords:
irreversible solvatochromic;
nanopaper based;
tpy;
solvatochromic nanopaper ... See more keywords
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Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.6b12810
Abstract: Photoluminescent coordination nanosheets (CONASHs) comprising three-way terpyridine (tpy) ligands and zinc(II) ions are created by allowing the two constitutive components to react with each other at a liquid/liquid interface. Taking advantage of bottom-up CONASHs, or…
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Keywords:
zinc;
tpy;
conash;
coordination nanosheets ... See more keywords
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Published in 2018 at "Chemical Society reviews"
DOI: 10.1039/c8cs00030a
Abstract: This overview represents a comprehensive summary of the recent developments in the growing field of terpyridine-based, discrete metallosupramolecular architectures. The N-heteroaromatic ligand [2,2':6',2'']terpyridine (tpy) presents a convergent N,N',N''-chelating donor set and has the ability to…
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Keywords:
self assembly;
constructs tailored;
tpy;
terpyridine based ... See more keywords
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Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d0nj05219a
Abstract: Heterometallic binuclear Ru–Pt and trinuclear Zn–Pt complexes were prepared via self-assembly by attaching PtII-tpy (tpy = 2,2′:6′,2′′-terpyridine) onto the RuII-tpy and ZnII-bis(tpy) moiety. The visible absorption bands for Ru–Pt complexes are primarily due to RuII…
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Keywords:
tpy;
two photon;
heterometallic complexes;
absorption ... See more keywords
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Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt00021g
Abstract: [Ir(tpy)2](PF6)3 (tpy = 2,2':6',2''-terpyridine) dissolved in CH3CN was found to exhibit dual color luminescent emission depending on the excitation wavelength. Specifically, blue and green emissions were obtained with excitation at 350 and 410 nm, respectively.…
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Keywords:
counter anion;
tpy;
ion pair;
dual emission ... See more keywords
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Published in 2023 at "Crystals"
DOI: 10.3390/cryst13060885
Abstract: Analysis of the data in the Cambridge Structural Database (CSD) for compounds containing an {M(tpy)X3} motif (tpy = 2,2’:6’,2”-terpyridine, M = any metal, X = F, Cl, Br, I) reveals 17 isostructural mononuclear [M(tpy)X3] compounds…
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Keywords:
crystal packing;
tpy motif;
compounds containing;
containing tpy ... See more keywords
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Published in 2022 at "Molecules"
DOI: 10.3390/molecules27196614
Abstract: Molecular hydrogen (H2) is considered one of the most promising fuels to decarbonize the industrial and transportation sectors, and its photocatalytic production from molecular catalysts is a research field that is still abounding. The search…
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Keywords:
catalyst light;
catalyst;
rhiii;
mono terpyridyl ... See more keywords