Systematic influence of electronic modification of ligand on the catalytic rate of water oxidation by a single-site Ru-based catalyst.
Sign Up to like & getrecommendations! Published in 2021 at "ChemSusChem"
DOI: 10.1002/cssc.202101657
Abstract: Catalytic water oxidation is an important process for the development of future clean energy solutions and energy storage. Despite a significant number of reported active catalysts, systematic control of the catalytic activity remains elusive. Here,… read more here.
Keywords: water oxidation; water; tpy; catalytic activity ... See more keywords
Terpyridine-based Three-dimensional Discrete Metallo-supramolecular Architectures.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200004
Abstract: Terpyridine (tpy)-based three-dimensional (3D) discrete metallo-supramolecular architectures, which are often inspired by the biological structures found in nature, have drawn significant attention from the community of metallo-supramolecular chemistry. Because of the linear tpy-M(II)-tpy connectivity, however,… read more here.
Keywords: discrete metallo; metallo supramolecular; metallo; tpy ... See more keywords
Kinetics and mechanistic study of electrocatalytic hydrogen evolution by [Co(Fc-tpy)2]2+
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114677
Abstract: Abstract This paper presents the synthesis and characterization of [Co(Fc-tpy)2](PF6)2 complex which acts as an active electrocatalyst for H2 evolution in both organic and aqueous media (Fc-tpy = 4′-ferrocenyl-2,2′:6′,2″-terpyridine). It exhibits the electrocatalytic H2 evolution in the… read more here.
Keywords: evolution; tpy; mechanistic study; kinetics mechanistic ... See more keywords
Photoinduced Reductive C–O Couplings from Unsymmetrical Bis-Cyclometalated Pt(IV) Dicarboxylato Complexes
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.4c03667
Abstract: Unsymmetrical bis-cyclometalated dicarboxylato complexes (OC-6-32)-[Pt(tpy)2(O2CR)2] [tpy = cyclometalated 2-(p-tolyl)pyridine, R = t-Bu (1), Me (2), Ph (3), CF3 (4)], are obtained from the reaction of cis-[Pt(tpy)2] with the appropriate PhI(O2CR)2 reagent. Treatment of complexes of… read more here.
Keywords: tpy; unsymmetrical bis; dicarboxylato complexes; bis cyclometalated ... See more keywords
Low-Temperature Observation of the Excited-State Decay of Ruthenium-(Mono-2,2′:6′,2″-Terpyridine) Ions with Innocent Ligands: DFT Modeling of an 3MLCT–3MC Intersystem Crossing Pathway
Sign Up to like & getrecommendations! Published in 2023 at "ACS Omega"
DOI: 10.1021/acsomega.3c01006
Abstract: The synthesis, electrochemistry, and photophysical characterization of five 2,2′:6′,2″-terpyridine ruthenium complexes (Ru-tpy complexes) is reported. The electrochemical and photophysical behavior varied depending on the ligands, i.e., amine (NH3), acetonitrile (AN), and bis(pyrazolyl)methane (bpm), for this… read more here.
Keywords: state; low temperature; terpyridine; tpy ... See more keywords
Irreversible Solvatochromic Zn-Nanopaper Based on Zn(II) Terpyridine Assembly and Oxidized Nanofibrillated Cellulose
Sign Up to like & getrecommendations! Published in 2018 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b01815
Abstract: A new irreversible solvatochromic Zn-nanopaper has been produced through the coordination-driven assembly of Zn(II)-terpyridine complex (Zn-tpy) on the surface of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-oxidized cellulose nanofibril (tCNF). The Zn-tpy as a photoactive center exhibits a changed emission… read more here.
Keywords: irreversible solvatochromic; nanopaper based; tpy; solvatochromic nanopaper ... See more keywords
Sustained, Selective, and Efficient Photochemical CO2 Reduction to Formate by Electron-Deficient Ruthenium Polypyridyl Complexes.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c14099
Abstract: Metal hydrides play a significant role in a variety of reactions, including chemical, electrochemical, and photochemical CO2 reduction. Molecular metal hydrides have the distinct advantage of allowing tunability of their hydricities by rational ligand modifications,… read more here.
Keywords: tpy; metal hydrides; metal; formate ... See more keywords
Coordination Nanosheets Based on Terpyridine-Zinc(II) Complexes: As Photoactive Host Materials.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.6b12810
Abstract: Photoluminescent coordination nanosheets (CONASHs) comprising three-way terpyridine (tpy) ligands and zinc(II) ions are created by allowing the two constitutive components to react with each other at a liquid/liquid interface. Taking advantage of bottom-up CONASHs, or… read more here.
Keywords: zinc; tpy; conash; coordination nanosheets ... See more keywords
Terpyridine-based metallosupramolecular constructs: tailored monomers to precise 2D-motifs and 3D-metallocages.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Society reviews"
DOI: 10.1039/c8cs00030a
Abstract: This overview represents a comprehensive summary of the recent developments in the growing field of terpyridine-based, discrete metallosupramolecular architectures. The N-heteroaromatic ligand [2,2':6',2'']terpyridine (tpy) presents a convergent N,N',N''-chelating donor set and has the ability to… read more here.
Keywords: self assembly; constructs tailored; tpy; terpyridine based ... See more keywords
Self-assembled heterometallic complexes showing enhanced two-photon absorption and their distribution in living cells
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d0nj05219a
Abstract: Heterometallic binuclear Ru–Pt and trinuclear Zn–Pt complexes were prepared via self-assembly by attaching PtII-tpy (tpy = 2,2′:6′,2′′-terpyridine) onto the RuII-tpy and ZnII-bis(tpy) moiety. The visible absorption bands for Ru–Pt complexes are primarily due to RuII… read more here.
Keywords: tpy; two photon; heterometallic complexes; absorption ... See more keywords
Dual emission from an iridium(III) complex/counter anion ion pair.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt00021g
Abstract: [Ir(tpy)2](PF6)3 (tpy = 2,2':6',2''-terpyridine) dissolved in CH3CN was found to exhibit dual color luminescent emission depending on the excitation wavelength. Specifically, blue and green emissions were obtained with excitation at 350 and 410 nm, respectively.… read more here.
Keywords: counter anion; tpy; ion pair; dual emission ... See more keywords