Stereocomplementary Synthesis of cis- and trans-2-(p-Bromophenyl)-5-methylthiazolidin-4-ones: Useful Umpolung-type Suzuki–Miyaura Cross-coupling Partner and Donor
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DOI: 10.1002/jhet.3141
Abstract: Novel cis- and trans-2-(p-bromophenyl)-5-methylthiazolidin-4-ones, S,N-containing heterocyclic compounds, were provided in a cis-stereocomplementary and trans-stereocomplementary synthetic manner. cis-Selective cyclo-condensation proceeded between 2-sulfanylpropanoic acid (thiolactic acid) and an imine derived from 4-bromobenzaldehyde and methylamine, whereas Ti(OiPr)4 and… read more here.
Keywords: methylthiazolidin ones; trans bromophenyl; bromophenyl methylthiazolidin; suzuki miyaura ... See more keywords