Trans‐philicity (trans‐influence/trans‐effect) ladders for square planar platinum(II) complexes constructed by 35Cl NMR probe
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DOI: 10.1002/jcc.26031
Abstract: The unified term of trans‐philicity is proposed to cover the trans‐effect/trans‐influence concepts. NMR trans‐philicity ladders are built for a broad series of square planar trans‐Pt(NH3)2(Cl)L and trans‐Pt(CO)2(Cl)L complexes employing 35Cl NMR probe and quantified by… read more here.
Keywords: trans influence; philicity; square planar; trans philicity ... See more keywords
Theoretical study on abnormal trans-effect of chloride, bromide and iodide ligands in iridium complexes
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DOI: 10.1016/j.comptc.2018.05.015
Abstract: Abstract Iridium complexes have been widely applied to energy and chemical industry, pharmaceutical industry, and organic synthesis. As a parameter reflecting the interaction between ligands and metal centers, trans-effect plays an important role in the… read more here.
Keywords: study; effect; iridium complexes; trans effect ... See more keywords
Very strong trans effect in ruthenacyclic carbamoyl complexes leads to ligand redistribution in phosphine derivatives
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.02.022
Abstract: Abstract The ruthenacyclic carbamoyl complexes [Ru (2-NHC(O)C5H4N) (CO)2(X) (NCMe)] (X = Cl, Br) (1) and [Ru (2-NHC(O)C5H4N) (CO)2 (2-S-Py)] (2) undergo substitution reactions with organophosphines to afford derivatives which are prone to a redistribution of the phosphine… read more here.
Keywords: redistribution; carbamoyl complexes; strong trans; trans effect ... See more keywords
The Janus face of high trans-effect carbenes in olefin metathesis: gateway to both productivity and decomposition
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DOI: 10.1039/d2sc00855f
Abstract: Ruthenium–cyclic(alkyl)(amino)carbene (CAAC) catalysts, used at ppm levels, can enable dramatically higher productivities in olefin metathesis than their N-heterocyclic carbene (NHC) predecessors. A key reason is the reduced susceptibility of the metallacyclobutane (MCB) intermediate to decomposition… read more here.
Keywords: olefin metathesis; metathesis; trans effect; decomposition ... See more keywords