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Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06331j
Abstract: 1,2-Ethenediols are deemed key intermediates in prebiotic and interstellar syntheses of carbohydrates. Here we present the gas-phase synthesis of these enediols, the high-energy tautomers of glycolaldehyde, trapped in cryogenic argon matrices. Importantly, upon photolysis at…
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Keywords:
ethenediol glycolaldehyde;
isolation photorearrangement;
photorearrangement cis;
matrix isolation ... See more keywords