Trans‐philicity (trans‐influence/trans‐effect) ladders for square planar platinum(II) complexes constructed by 35Cl NMR probe
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26031
Abstract: The unified term of trans‐philicity is proposed to cover the trans‐effect/trans‐influence concepts. NMR trans‐philicity ladders are built for a broad series of square planar trans‐Pt(NH3)2(Cl)L and trans‐Pt(CO)2(Cl)L complexes employing 35Cl NMR probe and quantified by… read more here.
Keywords: trans influence; philicity; square planar; trans philicity ... See more keywords
Trans Influence across a Metal-Metal Bond of a Paddle-Wheel Unit on Interaction with Gases in a Metal-Organic Framework.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02911
Abstract: Metal-organic frameworks (MOFs) are known as promising adsorbent materials that can recognize gases specifically. In the frameworks, gases favor interacting with specific binding sites such as open metal sites (OMSs), which can consist of various… read more here.
Keywords: paddle wheel; adsorption; trans influence; framework ... See more keywords
Trans Influence of Ligands on the Oxidation of Gold(I) Complexes.
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DOI: 10.1021/jacs.9b09363
Abstract: Gold(I) complexes are considered active species towards oxidative addition, and current understanding indicates a different mechanism in contrast to other late transition metals, but a rational understanding of the reactivity profile is lacking. Herein, we… read more here.
Keywords: trans influence; gold; tri; oxidative addition ... See more keywords
NMR probe effects on trans-philicity and trans-influence ladders in square planar Pt(ii) complexes
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DOI: 10.1039/d0nj01336f
Abstract: Quantitative trans-philicity ladders for a broad series of ligands in square planar trans-[Pt(PMe3)2(X)L]n (n = 0, 1, 2; X = H, CO, CH3, NH2, OH2, Cl) complexes are built employing the isotropic σiso(SO) X NMR… read more here.
Keywords: trans influence; square planar; philicity trans; trans philicity ... See more keywords