Synthesis and characterization of the trans(O6) isomer Ni(II) complex containing symmetrical edta-type ligand with mixed carboxylate and diamine rings: Quantum-mechanical evaluation of different isomers
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.118954
Abstract: Abstract The trans(O6) isomer (trans(O6) refer to two six-membered rings in trans position) of the [Ba(H2O)4][Ni(1,3-pddadp)]·4H2O (1,3-pddadp = 1,3-propanediamine-N,N′-diacetate-N,N′-di-3-propionate) was synthesized and spectroscopically characterized (IR, UV–Vis). The trans(O6) geometry was confirmed by X-ray diffraction analysis. Single crystal… read more here.
Keywords: trans isomer; edta type; analysis; geometry ... See more keywords
Light-Induced Transformation of the Aromatic Heptaene Antifungal Antibiotic Candicidin D into Its All-Trans Isomer.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of natural products"
DOI: 10.1021/acs.jnatprod.7b00821
Abstract: Illumination of the aromatic heptaene macrolide antifungal antibiotic candicicin D with UV light results in an isomerization of the molecule. The product formed after irradiation of the candicidin complex with UV light (λ = 365… read more here.
Keywords: antifungal antibiotic; aromatic heptaene; light induced; candicidin ... See more keywords
Spacer Cation Alloying of a Homoconformational Carboxylate trans Isomer to Boost in-Plane Ferroelectricity in a 2D Hybrid Perovskite.
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DOI: 10.1021/jacs.0c12513
Abstract: Two-dimensional (2D) hybrid perovskites of Ruddlesden-Popper (RP) lattices are recently booming as a vigorous class of ferroelectrics, whereas their intrinsic van der Waals gaps exert weak interactions that destabilize the layered motifs. Thus, it is… read more here.
Keywords: spacer; cation alloying; ferroelectricity; trans isomer ... See more keywords