Calculations on the non-classical β-hydride elimination observed in trans-(H)(OMe)-Ir(Ph)(PMe3)3: possible production and reaction of methyl formate
Sign Up to like & getrecommendations! Published in 2020 at "Canadian Journal of Chemistry"
DOI: 10.1139/cjc-2020-0313
Abstract: The octahedral trans hydrido-alkoxide complex trans-(H)(OMe)-Ir(Ph)(PMe3)3 (2-OCH3) was prepared by Milstein and coworkers by addition of methanol to Ir(Ph)(PMe3)3 (1). 2-OCH3 was discovered to undergo a methanol catalyzed outer-sphere carbonyl de-insertion in which a vacant… read more here.
Keywords: methyl formate; trans ome; reaction; och3 ... See more keywords