Cryptic Oxidative Transamination of Hydroxynaphthoquinone in Natural Product Biosynthesis.
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DOI: 10.1021/jacs.1c13074
Abstract: Pyridoxal 5'-phosphate (PLP)-dependent enzymes are a group of versatile enzymes that catalyze various reactions, but only a small number of them react with O2. Here, we report an unprecedented PLP-dependent enzyme, NphE, that catalyzes both… read more here.
Keywords: transamination; biosynthesis; cryptic oxidative; transamination hydroxynaphthoquinone ... See more keywords