Hydrogen Transfer Activation via Stabilization of Coordinatively Vacant Sites: Tuning Long-Range π-System Electronic Interaction between Ru(0) and NHC Pendants
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DOI: 10.1021/acs.organomet.8b00850
Abstract: The insertion of a pyridine substituent on the lateral chain of N-heterocyclic carbene ligands enhances the catalytic activity of [Ru(CO)2(cyclopentadienone)(NHC)] complexes, precursors of Shvo-type catalysts, toward the hydrogenation of 4-fluoroacetophenone in refluxing 2-propanol as hydrogen… read more here.
Keywords: hydrogen transfer; via stabilization; transfer activation; nhc ... See more keywords