Articles with "transfer hydrogenolysis" as a keyword



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Nitrogen-doped carbon-decorated copper catalyst for highly efficient transfer hydrogenolysis of 5-hydroxymethylfurfural to convertibly produce 2,5-dimethylfuran or 2,5-dimethyltetrahydrofuran

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Published in 2018 at "Applied Catalysis B: Environmental"

DOI: 10.1016/j.apcatb.2018.01.006

Abstract: Abstract Currently, highly efficient transformation of abundant and low-cost renewable raw biomass into high-quality biofuels and important chemicals is one of the most promising solutions to the current energy crisis, rapid consumption of fossil resources,… read more here.

Keywords: transfer hydrogenolysis; nitrogen doped; doped carbon; transfer ... See more keywords

Catalytic transfer hydrogenolysis of lignin into monophenols over platinum-rhenium supported on titanium dioxide using isopropanol as in situ hydrogen source.

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Published in 2019 at "Bioresource technology"

DOI: 10.1016/j.biortech.2019.01.132

Abstract: Using isopropanol as an in situ hydrogen donor, catalytic transfer hydrogenolysis of lignin into monomeric phenols was studied at mild conditions. The performance of catalysts and the effects of H2, temperature, and time on depolymerization… read more here.

Keywords: transfer hydrogenolysis; using isopropanol; catalytic transfer; situ hydrogen ... See more keywords
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Catalytic Transfer Hydrogenolysis/Hydrogenation of Biomass-Derived 5-Formyloxymethylfurfural to 2, 5-Dimethylfuran Over Ni–Cu Bimetallic Catalyst with Formic Acid As a Hydrogen Donor

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Published in 2019 at "Industrial & Engineering Chemistry Research"

DOI: 10.1021/acs.iecr.8b05960

Abstract: Compared to biomass-derived 5-hydroxymethylfurfural (HMF), 5-formyloxymethylfurfural (FMF) is highly potential as feedstock to produce 2, 5-dimethylfuran (DMF) due to its properties of higher stabi... read more here.

Keywords: biomass derived; transfer hydrogenolysis; biomass; hydrogenolysis hydrogenation ... See more keywords
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Catalytic Transfer Hydrogenolysis of Lignin-Derived Aromatic Ethers Promoted by Bimetallic Pd/Ni Systems

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Published in 2018 at "ACS Sustainable Chemistry & Engineering"

DOI: 10.1021/acssuschemeng.8b01593

Abstract: Catalytic transfer hydrogenolysis (CTH) of diphenyl ether (DPE), 2-phenethyl phenyl ether (PPE), and benzyl phenyl ether (BPE)—as model molecules of α-O-4 and β-O-4 as well as 4-O-5 lignin linkages—promoted by bimetallic Pd/Ni systems is reported.… read more here.

Keywords: transfer hydrogenolysis; catalytic transfer; promoted bimetallic; bimetallic systems ... See more keywords
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Catalytic self-transfer hydrogenolysis of lignin with endogenous hydrogen: road to the carbon-neutral future.

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Published in 2022 at "Chemical Society reviews"

DOI: 10.1039/d1cs00908g

Abstract: Due to the depletion of fossil sources, it is imperative to develop a sustainable and carbon-neutral biorefinery for supporting the fuel and chemical supply in modern society. Lignin, the only renewable aromatic source, is still… read more here.

Keywords: lignin; hydrogen; transfer hydrogenolysis; self transfer ... See more keywords
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Catalytic Transfer Hydrogenolysis Reactions for Lignin Valorization to Fuels and Chemicals

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Published in 2019 at "Catalysts"

DOI: 10.3390/catal9010043

Abstract: Lignocellulosic biomass is an abundant renewable source of chemicals and fuels. Lignin, one of biomass main structural components being widely available as by-product in the pulp and paper industry and in the process of second… read more here.

Keywords: reactions lignin; transfer hydrogenolysis; transfer; hydrogenolysis reactions ... See more keywords