Redox-Neutral Transformations of Carbon Dioxide Using Coordinatively Unsaturated Late Metal Silyl Amide Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03453
Abstract: Two-coordinate silylamido complexes of nickel and copper rapidly react with CO2 to selectively form a new cyanate ligand along with hexamethyldisiloxane byproducts. Mechanistic insight into these reactions was obtained from the synthesis of proposed intermediates,… read more here.
Keywords: carbon dioxide; dioxide using; neutral transformations; redox neutral ... See more keywords
Structural Transformations of a Carbon Nanomaterial under High-Energy Laser Irradiation
Sign Up to like & getrecommendations! Published in 2020 at "Russian Journal of General Chemistry"
DOI: 10.1134/s1070363220030317
Abstract: Abstract Pulsed-laser irradiation of a globular turbostratic carbon material under diverse conditions was carried. A TEM examination revealed formation of nanostructured particles (nanocapsules) under exposure to 1064 nm pulsed radiation at the power density of… read more here.
Keywords: transformations carbon; structural transformations; carbon nanomaterial; laser irradiation ... See more keywords