LAUSR

Facile C-H bond activation on a transient gallium imide.

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2 Published in 2022 at "Chemical communications"

DOI: 10.1039/d2cc01857h

Abstract: Reaction of NacNacGa with azide N3SiMe3 results in the generation of a transient imide NacNacGa(NSiMe3) that can cleave unactivated sp3 C-H and sp2 C-H bonds of different substrates, affording gallium amides. Pyridine, cyclohexanone, ethyl acetate,… read more here.

Keywords: activation transient; gallium; bond activation; facile bond ... See more keywords