Dual Pathways and Transient Intermediates Reveal Hydrolysis-Driven Assembly of Aluminum Keggin Clusters.
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DOI: 10.1021/acs.inorgchem.5c02626
Abstract: Despite the critical role of aluminum hydrolysis and condensation in the synthesis of aluminum-based compounds and their chemical behavior, experimental evidence regarding the formation and transformation pathways of species in solution remains scarce. This study… read more here.
Keywords: aluminum; hydrolysis driven; transient intermediates; pathways transient ... See more keywords
Identification of Transient Intermediates and Active Species in Atomic CZA Catalysts for CO2 Hydrogenation to Methanol
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DOI: 10.1021/jacs.5c08043
Abstract: Direct hydrogenation of carbon dioxide to methanol is a promising strategy for carbon capture and utilization (CCU). Copper–zinc–alumina (CZA) catalysts are widely used for this transformation, yet the nature of the active Cu and Zn… read more here.
Keywords: methanol; hydrogenation; transient intermediates; catalysts co2 ... See more keywords