Programmable Payload Release from Transient Polymer Microcapsules Triggered by a Specific Ion Coactivation Effect.
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DOI: 10.1021/jacs.7b11022
Abstract: Stimuli-responsive materials activated by a pair of molecular or ionic species are of interest in the design of chemical logic gates and signal amplification schemes. There are relatively few materials whose coactivated response has been… read more here.
Keywords: sica effect; specific ion; ion coactivation; effect ... See more keywords
Lewis Pairs as Highly Tunable Dynamic Crosslinks in Transient Polymer Networks.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b07452
Abstract: Classical Lewis pairs (LPs) between unhindered electron-poor Lewis acids (LAs) and electron-rich Lewis bases (LBs) present an overlooked motif with tremendous potential as dynamic crosslinks in transient polymer networks (TPNs) for self-healing and stimuli-responsive applications.… read more here.
Keywords: lewis pairs; crosslinks transient; polymer networks; dynamic crosslinks ... See more keywords