Bismuth Pyridine Dipyrrolide Complexes: a Transient Bi(II) Species Which Ring Opens Cyclic Ethers.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02314
Abstract: A family of group 15 MIII pyridine dipyrrolide complexes has been prepared and fully characterized; the reduction of these complexes was investigated with traditional strong metal reductants, which led either to over-reduction in the case… read more here.
Keywords: transient species; bismuth pyridine; pyridine dipyrrolide; complexes transient ... See more keywords
Molecular Identification of the Transient Species Mediating the Deactivation Dynamics of Solvated Guanosine and Deazaguanosine
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27030989
Abstract: Small structural alterations of the purine/pyrimidine core have been related to important photophysical changes, such as the loss of photostability. Similarly to canonical nucleobases, solute-solvent interactions can lead to a change in the excited state… read more here.
Keywords: deactivation; state; transient species; molecular identification ... See more keywords