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Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00597
Abstract: The formal two-electron reduction of the cyclo-tri(phosphonio)methanide dication 12+ results in a ring-opening reaction via C–P bond cleavage to yield the unique phosphanyl-functionalized carbodiphosphorane 2. In situ spectroelectrochemical investigations of the reduction of dication 12+…
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Keywords:
ring opening;
dication;
phosphonio methanide;
tri phosphonio ... See more keywords