Precision Synthesis of Polypeptides via Living Anionic Ring-Opening Polymerization of N-Carboxyanhydrides by Tri-thiourea Catalysts.
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DOI: 10.1021/jacs.2c10950
Abstract: The chemistry of α-amino acid N-carboxyanhydrides (NCAs) has a history of over 100 years, but precise and efficient ring-opening polymerization methods for NCAs remain highly needed to facilitate the studies of polypeptides─that is, mimics of… read more here.
Keywords: living anionic; tri thiourea; anionic ring; opening polymerization ... See more keywords