A Chiral Amine Transfer Approach to the Photocatalytic Asymmetric Synthesis of α-Trialkyl-α-tertiary Amines
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DOI: 10.1021/acs.orglett.2c04308
Abstract: A long-standing challenge within radical chemistry is that of controlling the absolute stereochemistry of the products. Here, we report the stereocontrolled addition of α-amino radicals reductively generated from imines via visible-light-mediated photoredox-catalysis to alkenes, giving… read more here.
Keywords: tertiary amines; transfer approach; chiral amine; trialkyl tertiary ... See more keywords