Gram-Scale Synthesis and Supramolecular Complex of Precursors of Clar’s Hydrocarbon Triangulene
Sign Up to like & getrecommendations! Published in 2019 at "Organic Letters"
DOI: 10.1021/acs.orglett.9b02683
Abstract: We present to date the most efficient gram-scale synthesis of triangulene-4,8-dione and 12-hydroxytriangulene-4,8-dione, the precursors of Clar’s hydrocarbon, in overall yields >50%. The direct dihydroprecursors of triangulene, obtained upon reduction of triangulene-4,8-dione, were stabilized in… read more here.
Keywords: gram scale; scale synthesis; triangulene; supramolecular complex ... See more keywords
Synthesis and characterization of triangulene.
Sign Up to like & getrecommendations! Published in 2017 at "Nature nanotechnology"
DOI: 10.1038/nnano.2016.305
Abstract: Triangulene, the smallest triplet-ground-state polybenzenoid (also known as Clar's hydrocarbon), has been an enigmatic molecule ever since its existence was first hypothesized. Despite containing an even number of carbons (22, in six fused benzene rings),… read more here.
Keywords: characterization triangulene; molecule; triangulene; synthesis characterization ... See more keywords