Direct Electrochemical P(V) to P(III) Reduction of Phosphine Oxide Facilitated by Triaryl Borates.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b07149
Abstract: Triaryl borate Lewis acids facilitate the direct two-electron reduction of the P(V) center of triphenylphosphine oxide (TPPO) to the P(III) center of triphenylphosphine at faradaic efficiencies of 37%. Insight from direct P(V) to P(III) reduction… read more here.
Keywords: reduction; triaryl borate; triaryl; iii reduction ... See more keywords
Highly flexible phosphabenzenes: a missing coordination mode of 2,4,6-triaryl-λ3-phosphinines.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc01817a
Abstract: The reaction of 2,4,6-triaryl-λ3-phosphinine-Cr(CO)3-π-complexes with [Rh(COD)2]BF4 leads to unusual diamagnetic Rh0-dimers, which contain two phosphinine-π-complexes acting as a bridging 2e--ligand towards the Rh2(CO)2 core. These compounds represent a missing coordination mode for the aromatic 6-membered… read more here.
Keywords: coordination mode; highly flexible; triaryl; missing coordination ... See more keywords