Direct Electrochemical P(V) to P(III) Reduction of Phosphine Oxide Facilitated by Triaryl Borates.
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DOI: 10.1021/jacs.8b07149
Abstract: Triaryl borate Lewis acids facilitate the direct two-electron reduction of the P(V) center of triphenylphosphine oxide (TPPO) to the P(III) center of triphenylphosphine at faradaic efficiencies of 37%. Insight from direct P(V) to P(III) reduction… read more here.
Keywords: reduction; triaryl borate; triaryl; iii reduction ... See more keywords