Palladium-Catalyzed Synthesis of 3,6-Diaryl-1-silylfulvenes: A Promising Entry for Preparing 1,3,6-Triarylfulvenes Bearing Three Different Aryl Groups.
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DOI: 10.1021/acs.orglett.3c00340
Abstract: We developed a synthetic methodology for preparing (E)-1,3,6-triarylfulvenes bearing three different aryl groups. The reaction of 1,4-diaryl-1-bromo-1,3-butadienes with silylacetylenes in the presence of a palladium catalyst produced (E)-3,6-diaryl-1-silyl-fulvenes in good to excellent yields. The (isopropoxy)silylated… read more here.
Keywords: aryl groups; bearing three; three different; preparing triarylfulvenes ... See more keywords