Heterolytic Bond Cleavage in a Scissile Triarylmethane Mechanophore.
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DOI: 10.1021/jacs.1c10004
Abstract: Covalent mechanophores display the cleavage of a weak covalent bond when a sufficiently high mechanical force is applied. Three different covalent bond breaking mechanisms have been documented thus far, including concerted, homolytic, and heterolytic scission.… read more here.
Keywords: cleavage; bond; bond cleavage; heterolytic bond ... See more keywords