Machine Learning‐Assisted Design of Nitrogen‐Rich Covalent Triazine Frameworks Photocatalysts
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202413453
Abstract: Covalent triazine frameworks (CTFs), noted for their rich nitrogen content, have attracted significant attention as promising photocatalysts. However, the structural complexity introduced by the diversity of nitrogen atoms in nitrogen‐rich CTFs poses a substantial challenge… read more here.
Keywords: covalent triazine; triazine frameworks; nitrogen rich; nitrogen ... See more keywords
The Exfoliation of Crystalline Covalent Triazine Frameworks by Glycerol Intercalation
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DOI: 10.1002/admi.202100374
Abstract: It is a huge challenge to exfoliate covalent triazine frameworks (CTFs) into large‐area CTF sheets, because of the ultrastrong triazine linkage and its high crystallinity. Herein, a glycerol intercalation strategy is reported to exfoliate bulk… read more here.
Keywords: glycerol intercalation; ctf hc1; triazine frameworks; covalent triazine ... See more keywords
High‐performance BCN‐C heterostructured electrocatalyst derived from covalent triazine frameworks for nitrogen reduction
Sign Up to like & getrecommendations! Published in 2024 at "AIChE Journal"
DOI: 10.1002/aic.18422
Abstract: Designing and synthesizing heterostructure‐based catalysis combining two‐dimensional (2D) materials has attracted enormous attention in materials chemistry, especially for electrocatalysis, due to their tunable electronic properties and structure. In this work, a boron carbon nitride (BCN)‐coupled… read more here.
Keywords: covalent triazine; triazine frameworks; bcn heterostructure; performance ... See more keywords
Rational Design of Fe/N/S-Doped Nanoporous Carbon Catalysts from Covalent Triazine Frameworks for Efficient Oxygen Reduction.
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DOI: 10.1002/cssc.201800855
Abstract: Porous organic polymers (POPs) are promising precursors for developing high performance transition metal-nitrogen-carbon (M/N/C) catalysts for the oxygen reduction reaction (ORR). The rational design of POP precursors remain a great challenge, because of the elusive… read more here.
Keywords: rational design; triazine frameworks; covalent triazine; carbon catalysts ... See more keywords
Effect of nitrogen atom introduction on the photocatalytic hydrogen evolution activity of the covalent triazine frameworks: experimental and theoretical study.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202200828
Abstract: The construction of high performance photocatalyst has always been explored. Covalent organic frameworks (COFs), especially keto-amine linked COFs, have many advantages, such as adjustable band gaps, π-π stacking structure, excellent response ability to visible light,… read more here.
Keywords: triazine frameworks; hydrogen; t3h ctf; triazine ... See more keywords
Construction of Fluorine- and Piperazine-Engineered Covalent Triazine Frameworks Towards Enhanced Dual-Ion Positive Electrode Performance.
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DOI: 10.1002/cssc.202201219
Abstract: Organic positive electrodes featuring lightweight, and tunable energy storage modes by molecular structure engineering have promising application prospects in dual-ion batteries. Herein, a series of highly porous covalent triazine frameworks (CTFs) were synthesized under ionothermal… read more here.
Keywords: performance; triazine frameworks; ion positive; dual ion ... See more keywords
Isometric Covalent Triazine Frameworks Derived Porous Carbons as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reactions.
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DOI: 10.1002/cssc.202201937
Abstract: Covalent triazine frameworks (CTFs) and their derived N-doped carbons have attracted tremendous attention due to their wide application in energy conversion and storage in the past few years. However, previous interests mainly focused on development… read more here.
Keywords: derived porous; triazine frameworks; oxygen reduction; porous carbons ... See more keywords
Crystalline Covalent Triazine Frameworks with Fibrous Morphology via a Low-Temperature Polycondensation of Planar Monomer.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202200984
Abstract: The morphology regulation of covalent triazine frameworks (CTFs) is a great challenge, which may be due to the difficulty in controlling its morphology by traditional synthesis methods. Herein, a general approach to fabricate morphology controllable… read more here.
Keywords: covalent triazine; fibrous morphology; morphology; triazine frameworks ... See more keywords
Immobilization of Ir(I) complex on covalent triazine frameworks for C H borylation reactions: A combined experimental and computational study
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2019.01.030
Abstract: Abstract Metal-modified covalent triazine frameworks (CTFs) have attracted considerable attention in heterogeneous catalysis due to their strong nitrogen-metal interactions exhibiting superior activity, stability and hence recyclability. Herein, we report on a post-metalation of a bipyridine-based… read more here.
Keywords: covalent triazine; triazine frameworks; immobilization complex; borylation ... See more keywords
Facile preparation of ultrafine Pd nanoparticles anchored on covalent triazine frameworks catalysts for efficient N-alkylation.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of colloid and interface science"
DOI: 10.1016/j.jcis.2021.08.059
Abstract: The fabrication of stable and efficient catalysts for green and economic catalytic transformation is significant. Here, highly stable covalent triazine frameworks (CTF-1) were used as the supporting material for anchoring ultrafine Pd nanoparticles (NPs) via… read more here.
Keywords: triazine; ultrafine nanoparticles; triazine frameworks; facile preparation ... See more keywords
Crystallization of Covalent Triazine Frameworks via a Heterogeneous Nucleation Approach for Efficient Photocatalytic Applications
Sign Up to like & getrecommendations! Published in 2021 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.0c03716
Abstract: Crystalline covalent triazine frameworks (CTFs) have shown intriguing applications in photoelectric fields. So far, a number of synthetic strategies based on homogeneous nucleation have been report... read more here.
Keywords: crystallization covalent; nucleation; covalent triazine; triazine frameworks ... See more keywords