Spin Switching with Triazolate-Strapped Ferrous Porphyrins.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b00349
Abstract: Fe(III) porphyrins bridged with 1,2,3-triazole ligands were synthesized. Upon deprotonation, the triazolate ion coordinates to the Fe(III) ion, forming an overall neutral high-spin Fe(III) porphyrin in which the triazolate serves both as an axial ligand… read more here.
Keywords: strapped ferrous; triazolate; triazolate strapped; spin ... See more keywords
Bidentate Triazolate-Based Ligand System: Synthesis, Coordination Modes, and Cooperative Bond Activation
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00775
Abstract: The 1,2,3-triazole ring represents a highly attractive and useful platform for ligand synthesis. In this work, we reveal the design, preparation, and properties of a novel bidentate triazolate-based ligand and its potential in cooperative metal–ligand… read more here.
Keywords: bond activation; ligand; triazolate; bidentate triazolate ... See more keywords