Spin Switching with Triazolate-Strapped Ferrous Porphyrins.
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DOI: 10.1021/acs.inorgchem.9b00349
Abstract: Fe(III) porphyrins bridged with 1,2,3-triazole ligands were synthesized. Upon deprotonation, the triazolate ion coordinates to the Fe(III) ion, forming an overall neutral high-spin Fe(III) porphyrin in which the triazolate serves both as an axial ligand… read more here.
Keywords: strapped ferrous; triazolate; triazolate strapped; spin ... See more keywords