Convergence of Competitive Azidation, Elimination vs Substitution, and Preferential Ring Formation: Metal-Free, One-Pot Route to Oxa-Ring Fused Triazoles from Functionalized Polyols
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DOI: 10.1021/acsomega.5c05041
Abstract: A series of polymesylated/polypropargylated polyols of different chain lengths were designed for the synthesis of the new varieties of 1,5-disubstituted 1,2,3-triazolyl fused bicyclic oxa-heterocycles under metal-free conditions. The orthogonally stable mesylated and propargylated polyol substrates… read more here.
Keywords: fused triazoles; triazoles functionalized; metal free; ring fused ... See more keywords