Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Triazoles with Internal Alkynes and Terminal Allenes.
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DOI: 10.1021/acs.orglett.7b03708
Abstract: The rhodium-catalyzed asymmetric N1-selective and regioselective coupling of triazole derivatives with internal alkynes and terminal allenes gives access to secondary and tertiary allylic triazoles in very good enantioselectivities. For this process, three new members of… read more here.
Keywords: terminal allenes; internal alkynes; rhodium catalyzed; alkynes terminal ... See more keywords