Synthesis of Iridium Tetrazolato, Triazolinato, and Triazolato Complexes by [3+2] Cycloaddition of Iridium(III) Azido Complexes with Unsaturated Nitriles
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DOI: 10.1021/acs.organomet.9b00031
Abstract: The diazido complexes [Ir(η5-C5Me5)(N3)2(PPh3)] (1a), [Ir(η5-C5Me5)(N3)2{κ(P)-R2PCH2CH═CH2}] (R = Ph (1b), iPr (1c)) have been synthesized and their [3+2] cycloaddition reaction toward tetracyanoet... read more here.
Keywords: iridium tetrazolato; tetrazolato triazolinato; synthesis iridium; triazolinato triazolato ... See more keywords