Influence of Anion and Crosslink Density on the Ionic Conductivity of 1,2,3-Triazolium-Based Poly(ionic liquid) Polyester Networks
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecular Chemistry and Physics"
DOI: 10.1002/macp.201700337
Abstract: Covalently crosslinked, 1,2,3-triazolium-containing poly(ionic liquid) networks are prepared using Michael addition polymerization. Crosslink density and counteranion are varied in order to decipher the relationships between poly(ionic liquid) (PIL) structure and their thermal, mechanical, and conductive… read more here.
Keywords: ionic conductivity; ionic liquid; crosslink density; triazolium ... See more keywords
Preparation and thermoresponsive properties of UCST-type glycopolypeptide bearing mannose pendants and 3-methyl-1,2,3-triazolium linkages in ethanol or ethanol/water solvent mixtures
Sign Up to like & getrecommendations! Published in 2017 at "Colloid and Polymer Science"
DOI: 10.1007/s00396-017-4064-2
Abstract: A series of glycopolypeptides with constant main-chain lengths and bearing various mannose pendants and 3-methyl-1,2,3-triazolium linkages were synthesized by N-alkylation, ion-exchange reaction, and subsequent deprotection. 1H NMR and FTIR analysis verified their molecular structures. Their… read more here.
Keywords: pendants methyl; methyl triazolium; triazolium linkages; mannose pendants ... See more keywords
Theoretical (density functional theory) studies on the structural, electronic and catalytic properties of the ionic liquid 4-amino-1H-1,2,4-triazolium nitrate
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2018.08.041
Abstract: Abstract Density functional theory calculations using B3LYP/6-311++G(2d,2p) level was used for investigation the geometry, electronic properties and catalytic activity of the ionic liquid 4-amino-1H-1,2,4-triazolium nitrate. Quantum theory of atoms in molecules adequately described the geometry… read more here.
Keywords: ionic liquid; theory; triazolium nitrate; triazolium ... See more keywords
1-Amine-1,2,3-triazolium salts with oxidizing anions: A new family of energetic materials with good performance
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.01.024
Abstract: Abstract A series of 1-amino-1,2,3-triazole (ATZ) based energetic nitrogen-rich salts are prepared by using acid-base neutralization reaction (1:1 M ratio), and fully characterized. Structures of the salts are recrystallized and determined by single-crystal X-ray diffraction, which… read more here.
Keywords: energetic materials; triazolium salts; amine triazolium; triazolium ... See more keywords
Electrosynthesis of 1,2,4-Triazolium Tetrafluoroborates.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c01651
Abstract: The synthesis of 1,2,4-triazolium tetrafluoroborates under electrochemical conditions is reported. The reaction is performed with stoichiometric amounts of HBF4, which converts starting materials to their corresponding cationic forms due to protonation. As a result, sufficient… read more here.
Keywords: electrosynthesis triazolium; triazolium; triazolium tetrafluoroborates;
Unidirectional Perpendicularly Aligned Lamella-Structured Oligosaccharide (A) ABA Triblock Elastomer (B) Thin Films Utilizing Triazolium+/TFSI– Ionic Nanochannels
Sign Up to like & getrecommendations! Published in 2022 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.1c00712
Abstract: We designed and synthesized high χ-low N-maltoheptaose-(triazolium+/N(SO2CF3)2–)-polyisoprene-(triazolium+/N(SO2CF3)2–)-maltoheptaose ABA triblock elastomers featuring triazolium+/N(SO2CF3)2– (TFSI–) counteranion ionic interfaces separating their constituting polymeric sub-blocks. Spin-coated and solvent-vapor-annealed (SVA) MH1.2k-(T+/TFSI–)-PI4.3k-(T+/TFSI–)-MH1.2k thin films demonstrate interface-induced charge cohesion through ca. 1… read more here.
Keywords: thin films; tfsi; aba triblock; ionic nanochannels ... See more keywords
1-Methyl-4-R-1,2,4-triazolium (R = −CH2CH2OCH3, −CH2COOCH2CH3)-Based Ionic Liquids as Plasticizers for Solid Propellants
Sign Up to like & getrecommendations! Published in 2023 at "ACS Omega"
DOI: 10.1021/acsomega.3c00256
Abstract: In this paper, a series of energetic ionic liquid plasticizers of 1-methyl-4-methoxyethyl-1,2,4-triazolium chloride (1), 1-methyl-4-methoxyethyl-1,2,4-triazolium bis(trifluoromethylsulfonyl)imide (1a), 1-methyl-4-methoxyethyl-1,2,4-triazolium nitrate (1b), 1-methyl-4-ethyl acetate-1,2,4-triazolium chloride (2), 1-methyl-4-ethyl acetate-1,2,4-triazolium bis(trifluoromethylsulfonyl)imide (2a), and 1-methyl-4-ethyl acetate-1,2,4-triazolium nitrate (2b) were synthesized… read more here.
Keywords: htpb; ionic liquids; methoxyethyl triazolium; methyl methoxyethyl ... See more keywords
Cationic and dicationic 1,2,3-triazolium-based poly(ethylene glycol ionic liquid)s
Sign Up to like & getrecommendations! Published in 2017 at "Polymer Chemistry"
DOI: 10.1039/c6py02030e
Abstract: We report the synthesis of two novel poly(ionic liquid)s having poly(ethylene glycol) main chains and side chains having either one or two 1,2,3-triazolium cations with triethylene glycol spacers and bis(trifluoromethylsulfonyl)imide counter anion(s). Both ion conducting… read more here.
Keywords: triazolium; poly ethylene; ethylene glycol; spectroscopy ... See more keywords
Novel 1,2,3-triazolium-functionalized inulin derivatives: synthesis, free radical-scavenging activity, and antifungal activity
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c7ra08244d
Abstract: A new class of inulin derivatives possessing 1,2,3-triazolium charged units by associating “click reaction” with efficient 1,2,3-triazole quaternization were designed and synthesized. After the chemical modification, all the inulin derivatives showed good solubility in water,… read more here.
Keywords: inulin derivatives; scavenging activity; radical scavenging; triazolium ... See more keywords
Recent Advances in Enantioselective Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes (NHCs) Containing Triazolium Motifs
Sign Up to like & getrecommendations! Published in 2022 at "Synthesis"
DOI: 10.1055/a-1856-5688
Abstract: N-Heterocyclic carbenes (NHCs) containing triazolium motifs have emerged as a powerful tool in organocatalysis. Recently, various NHC pre-catalyst mediated organic transformations have been developed successfully. This article aims to compile the current state of knowledge… read more here.
Keywords: heterocyclic carbenes; triazolium motifs; carbenes nhcs; triazolium ... See more keywords
Synthesis and application of novel carbohydrate-based ammonium and triazolium salts
Sign Up to like & getrecommendations! Published in 2019 at "Synthetic Communications"
DOI: 10.1080/00397911.2019.1625403
Abstract: Abstract The synthesis of nine new carbohydrate-based quaternary ammonium salts and two new triazolium salts starting from d-glucose has been accomplished. Our synthesis utilized the regio- and stereoselective ring opening reaction of 2,3-anhydro sugars by… read more here.
Keywords: carbohydrate based; triazolium; triazolium salts; ammonium triazolium ... See more keywords