1-Amine-1,2,3-triazolium salts with oxidizing anions: A new family of energetic materials with good performance
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.01.024
Abstract: Abstract A series of 1-amino-1,2,3-triazole (ATZ) based energetic nitrogen-rich salts are prepared by using acid-base neutralization reaction (1:1 M ratio), and fully characterized. Structures of the salts are recrystallized and determined by single-crystal X-ray diffraction, which… read more here.
Keywords: energetic materials; triazolium salts; amine triazolium; triazolium ... See more keywords
Triazolium Salts as Lewis Acid Catalysts.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01108
Abstract: We describe a new type of nitrenium-based Lewis acids: tetraaryl-1,2,3-triazolium salts. These were fully characterized by NMR and X-ray crystallography. The Gutmann-Beckett acidity numbers were determined to be up to 35.6, which is high compared… read more here.
Keywords: lewis acid; triazolium salts; acid catalysts; salts lewis ... See more keywords
An Alternative Method for the Synthesis of N-Pentafluorophenyl Triazolium Salts.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02863
Abstract: A route for the synthesis of 1,2,4-triazolium salts via oxidation of a thione precursor is demonstrated. N-Pentafluorophenyl-substituted salts are produced in 20-63% overall yields. Isolation and purification of the azolium salts are simplified compared to… read more here.
Keywords: triazolium salts; method synthesis; alternative method; synthesis ... See more keywords
Synthesis and application of novel carbohydrate-based ammonium and triazolium salts
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DOI: 10.1080/00397911.2019.1625403
Abstract: Abstract The synthesis of nine new carbohydrate-based quaternary ammonium salts and two new triazolium salts starting from d-glucose has been accomplished. Our synthesis utilized the regio- and stereoselective ring opening reaction of 2,3-anhydro sugars by… read more here.
Keywords: carbohydrate based; triazolium; triazolium salts; ammonium triazolium ... See more keywords
Ion Transport Properties and Ionicity of 1,3-Dimethyl-1,2,3-Triazolium Salts with Fluorinated Anions
Sign Up to like & getrecommendations! Published in 2018 at "Materials"
DOI: 10.3390/ma11091723
Abstract: 1,2,3-Triazolium salts are an important class of materials with a plethora of sophisticated applications. A series of three novel 1,3-dimethyl-1,2,3-triazolium salts with fluorine, containing anions of various size, is synthesized by methylation of 1,2,3-triazole. Their… read more here.
Keywords: ion transport; triazolium salts; dimethyl triazolium; triazolium ... See more keywords