Synthesis and photochemical study of tricarbonyl and dicarbonyl derivatives of 3-cymantrenylalkylisothioureas
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121465
Abstract: Abstract A series of 3-cymantrenylalkylisothioureas (2) was synthesized. DFT calculations showed that compounds 2 in solutions are dimers. The photolysis of 2 was studied by IR, UV–vis and NMR spectroscopic methods. Irradiation of compounds 2… read more here.
Keywords: dicarbonyl; synthesis photochemical; photochemical study; study tricarbonyl ... See more keywords
Insights into the Fluxional Processes of Monomethylcyclohexenyl Manganese Tricarbonyl
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DOI: 10.3390/molecules28073232
Abstract: Multiple fluxional processes of 6-monomethylcyclohexenylmanganese tricarbonyl [(6-MeC6H8)Mn(CO)3, complex 1] and 5-monomethylcyclohexenylmanganese tricarbonyl [(5-MeC6H8)Mn(CO)3, complex 2] have been explored using density functional theory (DFT) computations. The contributions of four agostomers—1, 2, 3, and 4—to the (MeC6H8)Mn(CO)3… read more here.
Keywords: monomethylcyclohexenyl manganese; processes monomethylcyclohexenyl; tricarbonyl; manganese tricarbonyl ... See more keywords