Asymmetric ruthenium tricarbonyl cyclopentadienone complexes; synthesis and application to asymmetric hydrogenation of ketones
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DOI: 10.1016/j.ica.2019.119043
Abstract: Abstract A series of enantiomerically-pure ruthenium tricarbonyl cyclopentadienone complexes were prepared via the cyclisation of C2-symmetric dialkynes with Ru3(CO)12. Four complexes were characterised by X-ray crystallography and a hydride derivative of one of these was… read more here.
Keywords: asymmetric hydrogenation; ruthenium tricarbonyl; tricarbonyl cyclopentadienone; cyclopentadienone complexes ... See more keywords