Boryl Radicals Enabled a Three-Step Sequence to Assemble All-Carbon Quaternary Centers from Activated Trichloromethyl Groups.
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DOI: 10.1021/jacs.2c05798
Abstract: The construction of diversely substituted all-carbon quaternary centers has been a longstanding challenge in organic synthesis. Methods that add three alkyl substituents to a simple C(sp3) atom rely heavily on lengthy multiple processes, which usually… read more here.
Keywords: step; carbon; carbon quaternary; trichloromethyl groups ... See more keywords